2 research outputs found
The electrorheology of suspensions consisting of Na-Fluorohectorite synthetic clay particles in silicon oil
Under application of an electric field greater than a triggering electric
field kV/mm, suspensions obtained by dispersing particles of the
synthetic clay fluoro-hectorite in a silicon oil, aggregate into chain- and/or
column-like structures parallel to the applied electric field. This
micro-structuring results in a transition in the suspensions' rheological
behavior, from a Newtonian-like behavior to a shear-thinning rheology with a
significant yield stress. This behavior is studied as a function of particle
volume fraction and strength of the applied electric field, . The steady
shear flow curves are observed to scale onto a master curve with respect to
, in a manner similar to what was recently found for suspensions of laponite
clay [42]. In the case of Na-fluorohectorite, the corresponding dynamic yield
stress is demonstrated to scale with respect to as a power law with an
exponent , while the static yield stress inferred from
constant shear stress tests exhibits a similar behavior with . The suspensions are also studied in the framework of thixotropic fluids:
the bifurcation in the rheology behavior when letting the system flow and
evolve under a constant applied shear stress is characterized, and a
bifurcation yield stress, estimated as the applied shear stress at which
viscosity bifurcation occurs, is measured to scale as with to 0.6. All measured yield stresses increase with the particle
fraction of the suspension. For the static yield stress, a scaling law
, with , is found. The results are found to be
reasonably consistent with each other. Their similarities with-, and
discrepancies to- results obtained on laponite-oil suspensions are discussed
Electrorheological Suspensions of Laponite in Oil: Rheometry Studies
International audienceWe have studied the effect of an external direct current (DC) electric field (1 kV/mm) on the rheological properties of colloidal suspensions consisting of aggregates of laponite particles in a silicone oil. Microscopy observations show that, under application of an electric field greater than a triggering electric field Ec 0.6 kV/mm, laponite aggregates assemble into chain- and/or columnlike structures in the oil. Without an applied electric field, the steady-state shear behavior of such suspensions is Newtonian-like. Under application of an electric field larger than Ec, it changes dramatically as a result of the changes in the microstructure: a significant yield stress is measured, and under continuous shear the fluid is shear-thinning. The rheological properties, in particular the dynamic and static shear stress, were studied as a function of particle volume fraction for various strengths (including null) of the applied electric field. The flow curves at constant shear rate can be scaled with respect to both the particle fraction and electric field strength onto a master curve. This scaling is consistent with simple scaling arguments. The shape of the master curve accounts for the system's complexity; it approaches a standard power-law model at high Mason numbers. Both dynamic and static yield stresses are observed to depend on the particle fraction — and electric field E as —âER, with R 1.85 and â 1 and 1.70 for the dynamic and static yield stresses, respectively. The yield stress was also determined as the critical stress at which there occurs a bifurcation in the rheological behavior of suspensions that are submitted to a constant shear stress; a scaling law with R 1.84 and â 1.70 was obtained. The effectiveness of the latter technique confirms that such electrorheological (ER) fluids can be studied in the framework of thixotropic fluids. The method is very reproducible; we suggest that it could be used routinely for studying ER fluids. The measured overall yield stress behavior of the suspensions may be explained in terms of standard conduction models for electrorheological systems. Interesting prospects include using such systems for guided self-assembly of clay nanoparticles